We offer halal and kosher polyvinyl acetate made in an iso9001, iso22000 fssc22000 and cgmp certified facility. Eu risk assessment vinyl acetate summary, 2008 8 copolymers. Polyvinyl acetate sds ghs, msds sheet of manufacturers. Material safety data sheet msds vinyl acetate monomer s. It is very flammable and may be ignited by heat, sparks, or flames. Msds of ethylene vinyl acetate emulsion ethylene vinyl acetate emulsion da128h download filepdf. Vinyl acetate monomer vam vinyl acetate acetic acid, vinyl. Vinyl acetate monomer is stored in mild steel storage tanks andor new or reconditioned steel drums and can be transported by bulk vessels or tank trucks. Parchem is open and ready to supply materials 18002823982 read more. Undergoes violent or explosive reactions with 2aminoethanol, chlorosulfonic acid, ethylenediamine, mineral acids hydrochloric acid, hydrofluoric acid, nitric acid, sulfuric acid, oleum, and peroxides lewis, 3rd ed. The chemical formula for vinyl acetate isc h o, and its molecular weight is 86. Vinyl acetate is used to make other industrial chemicals. Vinyl acetate ld50 2900 mgkg rat ld50 2335 mgkg rabbit lc50 3680 ppm rat 4 h lc50 11.
Vinyl acetate current prices petrochemicals prices database. Inhalation of vapors may result in dizziness or suffocation. Vinyl acetate monomer vam is a high volume building block chemical used in the manufacture of polyvinyl acetate or vinyl acetate copolymers. Ethylenevinyl acetate copolymer 14% vinyl acetate catalog numbers. Us2431554a us560300a us56030044a us2431554a us 2431554 a us2431554 a us 2431554a us 560300 a us560300 a us 560300a us 56030044 a us56030044 a us 56030044a us 2431554 a us2431554 a us 2431554a authority us united states prior art keywords vinyl acetate liquid scrubbing distillation impurities prior art date 19441025 legal status the legal status is an assumption and is. Vinyl acetate monomer is a widely used chemical intermediate thats found in a number of resins, plastic products, coatings, adhesives, paints, emulsion polymers, and acrylic fibers use. Broadly speaking, there are three different types of eva copolymer, which differ in the vinyl acetate va content and the way the materials are used. Acute exposure to vinyl acetate monomer may require decontamination and life support for the victims. It is a colorless liquid with a sweet, fruity smell, soluble in most organic solvents, but only slightly soluble in water.
The invention relates to vinyl acetateethylene copolymer emulsion vae emulsion and a synthesis method thereof. Ethylene vinyl alcohol can be used to produce gas barrier layers in coextruded packaging. Material safety data sheet of vinyl acetate monomer slideshare. Safety data sheet according to regulation ec no 19072006 and. Vam can be polymerized in mass, solution, suspension or emulsion. Keep polyvinyl acetate in a well closed container stored under cold to warm conditions, 2 to 40 c, 36 to 104f in a ventilated area. Ethylenevinyl acetate eva, also known as poly ethylenevinyl acetate peva, is the copolymer of ethylene and vinyl acetate. Rovace vinyl acetate polymers and vinyl acetate acrylic. Vinyl acetate occurs as residual monomer in homo and copolymers based on vinyl acetate and in products or formulations based on these polymers. It is a clear, colorless liquid with a sweet, fruity smell. Vinyl acetate monomer also known as acetic acid ethenyl ester, acetic acid ethylene ether, acetoxyethene, 1acetoxyethylene, ethenyl ethanoate, ethenyl acetate, and acetic acid vinyl ester is a colourless mobile liquid with a pungent odour.
Vinyl acetate,product center,shandong xinglu biological technology co. Fire hazard, reactive, immediate acute health hazard, delayed chronic health hazard. Vinyl acetate with an inhibitor level of 35 ppm hydroquinone should not be stored longer than six months at 2127 deg c 7080 deg f, or longer than one year with 1417 ppm hydroquinone. These polymers are the base for many industrial and consumer products as well as for other polymers. Vinyl acetate monomer supplier distributor cas 108054. Find msds or sds, a coa, data sheets and more information. Section 1 chemical product and company identification. Vinyl acetate polymers and vinyl acetate acrylic copolymers are used for a wide range of applications including paints, bond coats, binders, pigmented paper coatings, textiles, and nonwovens. Vinyl acetate is an industrial chemical that is produced in large amounts in the united states. Cdc niosh pocket guide to chemical hazards vinyl acetate. Vinyl acetate monomer polyvinyl chloride materials.
Vinyl acetate monomer vam is used for the production of polymer emulsions of various types, which are base resins for waterbased paints, adhesives, paper coatings and textile finishes. Safety and handling considerations to obtain a material safety data sheet msds or sds for vinyl acetate monomer or a safe. When handled properly, vam can be stored, transported and otherwise managed safely. Ethylene vinyl acetate copolymers are used to produce flexible films, coatings, adhesives, moldings and insulation. View or download the vinyl acetate msds material safety data sheet or sds for 803184 from merck. Forms explosive vinyl acetate ozonide on contact with ozone. Vam, vinyl acetate monomer, ethenyl acetate is an organic compound, an important vinyl ester, used in the manufacture of many polymers and resins. Vinyl acetate monomer, vinyl acetate monomer supplier, vinyl acetate monomer distributor, cas 108054, vinyl acetate monomer manufacturer, vinyl acetate monomer wholesale skip to main content covid19 status. Vinyl acetate monomer vam is a key intermediate used in the making of a number of polymers and resins for adhesives, coatings, paints, films. Wear appropriate protective eyeglasses or chemical safety goggles as described by oshas eye and face protection regulations in 29 cfr 1910. Vinyl acetate emulsion polymerization and copolymerization. Before using or handling vinyl acetate monomer vam, read the material safety data sheet.
Vinyl acetate,product center,shandong xinglu biological. These polymers are used to produce adhesives, paints, paper coatings, and textile finishes. Material safety data sheet or sds for vinyl acetate 803184 from merck for download or viewing in the browser. The clp regulation makes sure that the hazards presented by chemicals are clearly communicated to. Cn102030858b vinyl acetateethylene copolymer emulsion. Ethylenevinyl acetate copolymer eva is a copolymer of ethylene and vinyl acetate as shown in fig. Page 6 of 7 msds vinyl acetate monomer no increase in tumour incidence was found in rats administered vinyl acetate in the drinkingwater in utero and then for life. Ethylene vinyl acetate eva copolymer is a redispersible polymer, a vailable as a free flowing powder that can easily be redispersed to form a latex dispersion some applications require a 100% dry solids polymer that can be premixed with other solid additives. The hazard classification and labelling section shows the hazards of a substance based on the standardised system of statements and pictograms established under the clp classification labelling and packaging regulation. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in uae, europe, africa, usa. Worker exposure is possible in manufacturing facilities or facilities that use these polymers. Astm d5594 18a standard test method for determination of.
The synthesis method comprises the processes of preemulsification, emulsion polymerization reaction, finishing and defoaming. Sampling and analytical methods vinyl acetate organic. Identification product name vinyl acetate, stabilized cat no. Some grades are available with antiblock and slip additives. It is a colorless liquid with a sweet, fruity smell, soluble in most organic solvents, but. Vinyl acetate is a volatile liquid that polymerizes in light to a colorless, transparent mass and usually contains an inhibitor, such as hydroquinone. The invention is characterized in that complex emulsifying agents added into a reaction system include a nonion emulsifying agent, an anion.
Vinyl acetate monomer safety data sheet international vinyl acetate company safety data sheet according to regulation ec no. Since vinyl alcohol is highly unstable with respect to acetaldehyde, the preparation of vinyl acetate is more complex than the synthesis of other acetate esters. Vinyl acetate sds safety data sheet for vinyl acetate 803184. Vinyl acetate polymers and vinyl acetateacrylic copolymers are used for a wide range of applications including paints, bond coats, binders, pigmented paper coatings, textiles, and nonwovens. The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst. Msds, safety data sheet sds and any other materials provided. Ac183250000, ac183250010, ac183250250, ac183255000 synonyms.
Vinyl acetate monomer free download as powerpoint presentation. Before using or handling vinyl acetate monomer vam, read the material safety data sheet msds, safety data sheet sds and any other materials provided by your supplier. More specifically, vam is a monomer for synthesis of nitrile rubber, pvac emulsions, pvoh, eva copolymers, vinyl chloridevinyl acetate copolymers, pvbl, and vinyl acetateacrylonitrile. Jul 23, 2019 vinyl acetate monomer by lyondellbasell is a chemical building block used to manufacture a wide variety of adhesives. Ethenyl acetate recommended use laboratory chemicals. These chemicals are used mainly to make glues for the packaging.
O5057fb115 casno 108054 synonyms ethenyl ethanoate. Vinyl acetate monomer is also used to produce gas barrier layers in coextruded packaging. Astm d559418a, standard test method for determination of the vinyl acetate content of ethylene vinyl acetate eva copolymers by fourier transform infrared spectroscopy ftir, astm international, west conshohocken, pa, 2018. Vinyl acetate is used primarily in polymerization processes to produce polymers and copolymers such as polyvinyl acetate, polyvinyl alcohol, and vinyl chloridevinyl acetate.
Us2431554a purification of vinyl acetate by distillation. Please ensure that this msds is given to, and explained to people using this product. Guide is intended to be used in conjunction with the manufacturers information. Safety data sheet creation date 21sep2009 revision date 25apr2019 revision number 4 1. Material safety data sheet or sds for vinyl acetate 803184 from milliporesigma for download or viewing in the browser. The weight percent of vinyl acetate usually varies from 10 to 40%, with the remainder being ethylene. Signs and symptoms of acute vinyl acetate monomer exposure. Vinyl acetate vapors are uninhibited and may form polymers in vents or flame arrestors of storage tanks, resulting in plugging of vents. Material safety data sheet polyvinyl acetate lattice. Product and company information hoehn plastics inc. Material safety data sheet of vinyl acetate monomer. Vinyl acetate monomer safety data sheet international. Weight percent vinyl acetate varies from 10 to 40 %.
Vinyl acetate monomer may irritate the skin, eyes, and respiratory tract. Ethylene vinyl acetate an overview sciencedirect topics. Vinyl acetate emulsion polymerization and copolymerization with acrylic monomers provides a collection and logical organization of the published data much of it formerly found fragmented throughout various journals and little of it referenced in general emulsion polymerization books. The basis for the proposed limits is an epidemiologic report by deese and joyner 1969ex. The substance identity section is calculated from substance identification information from all echa databases. Material safety data sheet polyvinyl acetate, average m. Vinyl acetate is a particularly interesting substrate, since, as mentioned earlier, it gives 2acetoxypropanal, a precursor in the strecker synthesis of threonine. Sigmaaldrich offers a number of vinyl acetate products. Uses advised against food, drug, pesticide or biocidal product use. Material safety data sheet poly vinyl acetate, average m. Containers of this material may be hazardous when empty since they retain product residues dust, solids. Vinyl acetate is the acetate ester of vinyl alcohol.